Technical sciences/1. Metallurgy

 

         Abdrakhmanov Ye.S., Bykov P.Î.,         Bogomolov À.V., Kulumbayev N.Ê., Mukanov R.B.

Pavlodar State University named after S. Toraigyrov, Kazakhstan

Ecological aspects of use of Ekibastuz high-ash coal

Practical and rational use of raw material resources to stimulate growth in industrial production is one of basic requirements of Republic of Kazakhstan government in national economy. One of progressive methods to solve this problem is lumping. Significance of this study is extension of application field of Ekibastuz coal as an additive while lumping ore.

Lumping is conversion of fine-grained mineral resources into lump product due to mechanical and (or) thermal influence with application of special additives or without them. Briquetting, a physical and chemical process of processing of mineral resources, which is one of modification of lumping, allows to obtain sorted product stable in mechanical and thermal terms, namely, briquette with certain geometric shape, size and weight. The main goal of briquetting is disposal of fine-grained mineral resources and a chance to obtain high quality product out of them for household and industrial use.

Republic of Kazakhstan ranks 8th place worldwide for coal reserves. In Kazakhstan, 155 known coal deposits are explored and over 40 of them are with about 35.8 bln. tons of commercial reserves (3.6 % of world reserves). The most large coal basins are Ekibastuz (12.5 bln. tons), Karaganda (9.3 bln. tons) and Turgai (5.8 bln. tons).

Ekibastuz coal basin is developed using open-cut mining method which in its turn negatively affects the environmental situation of the region. Polluting factors are stripping operations and spoil dump after them. One of the most heavy polluting factors is transfer of coal dust and fines from open coal mines and spoil dump by wind. Particles transferred are precipitated at nearby areas. This fact is harmful to lands which are suitable for agricultural business.

Use of coal dust and fines accumulated for production of coal briquette is one of effective ways of solution of the problem.

Given the attractiveness of the idea, production of fuel briquette has not such a long history. The whole idea has become actual and acute only in recent years due to significant growth in fuel prices including coal products. Most of the efforts to organize production of coal briquettes was brought to naught either by expensive technology or low quality and bad characteristics of briquettes obtained due to application of cheap and bad combustible binding agents which greatly increased ash content and reduced sales effectiveness. The essence of the idea is obtaining of briquettes from coal fines and dust of high-ash coal of Ekibastuz deposit with possible subsequent coking.

The essence of the idea is obtaining of briquettes from coal fines and dust of high-ash coal of Ekibastuz deposit with possible subsequent coking by increase of carbon content, namely, in heating capacity. For this purpose, it is planned to use the recently developed technology for obtaining technical carbon by processing general mechanical rubber waste. Preliminary experiments carried out clearly demonstrated suitability of technical carbon for upgrade of fuel and coking briquettes. Thus, by the way, we solve the problem of disposal of general mechanical rubber waste which is known to be the most popular type of waste.

At the time being, one of the main problems of briquetting is impossibility of getting of briquettes without adding non-combustible binding agents which in their turn will far more increase ash content of briquettes. As a know-how of this project it is analyzed a possibility of obtaining processed organic products of bovine cattle byproducts as binding agents or some oil refining byproducts which are combustibles and will not reduce percentage of briquette heating capacity.

According to their intended use, coal briquettes divided into: household and industrial ones.

The main consumer of household briquettes is population purchasing them in bulk or pre-packed in bags with small weights. In order to provide appropriate thermal and mechanical strength as well as        smokelessness, briquettes are undergone a heat treatment. Industrial briquettes are used as a raw material for semi coking (brown coal) and coking (hardcoal and brown coal). Hardcoal briquettes can serve as heat-insulating material and main raw material for manufacture of different types of electrodes.

Perspective plans for development of national economy pose important tasks for improvement of briquette production. Firstly, it is study of simple and effective ways to increase percentage and quality of coal briquettes produced and widening of their application fields not only as a power plant and a household fuel but also as a raw material for metallurgic process, semi coking, chemical processing.

Briquetting of Ekibastuz coal fines with binding agents should be further used in creation of new technologies for briquetting of composite materials of power plant and coking coals. The special task for hardcoal briquetting is development of cost-saving, cheap, non-toxic binding agents, attraction of binding agents of mineral origin for this purpose and development of special additives, which improve mechanical and thermal properties of briquettes. A new trend in lumping of hardcoals before coking takes an essential role in briquetting of hardcoals. In this case, non-sintering types of hardcoals can be used in coking stock.  Briquetting provides maximum close contact of coal particles and their compaction in briquettes. Briquetting is one of perspective production trends providing high potential for fuel and energy sector, iron and steel industry and non-ferrous metal industry, disposal of different production wastes including general mechanical rubber goods.

Ekibastuz coal can contain about 46-67% of ballast. It means that when combusting 1 kg of coal the heat can be generated only by 54-33% of fuel, the rest turns to ash. That is why coal before briquetting should be upgraded.

The method offered for upgrading of Ekibastuz coal is the method for increase of carbon percentage in fuel by way of mixing of coal fine with smut. Mechanical rubber and high quality smut contains 96-98 % of carbon.

For this purpose a developed technology is used to obtain carbon by processing of mechanical rubber wastes. The experiments carried out clearly demonstrated suitability of technical carbon for upgrading of fuel and coking briquettes. As a result of mixing of coal fine and smut we reduced ash percentage in fuel down to 15-17 %.

Implication of this project has great perspectives in national and international scale. During preliminary studies and analyzes of Ekibastuz coal by a team of authors it was established that, in main volume, about 37% of coal extracted is 0.1-1.6 mm size of coal fine. It allows to obtain fuel and coking briquettes with minimum costs for their preparation which may suggest high practical importance for the project and possibility of further commercialization.

Project results will be of interest to companies dealing with coal extraction and sale of coal as well as to consumers who accumulate off-grade coal fine.

References:

1                   Bykhover N. À. Economics of mineral raw materials, v. 1-3. Ì., 1967-1971. World mineral resources. Ì., 1997.

2                   Republic of Kazakhstan government decree of ¹644 of June 28, 2008. On prospective of coal industry development in Republic of Kazakhstan up to 2020.

3                   Palygunov P. P., Sumarokov Ì. V. Disposal of industrial waste. – Ì. : Stroiizdat, 1990. – 352 p. : il. – (Environmental protection).

4                   Trozzi Ê., Berdovki Ya., Verkhoyev P., Weldt Ê., Pasina D., Jones H., Renz Î., Oertel D. and Woodfield Ì. Uncontrolled emissions of processes using solid fuel: Conversion of solid fuel. Guidelines of ÅÌÅÏ/ÅÀÎÑ for emission inventory, 2009.

5                   Kaliakparov À. G., Ph.D. thesis in Engineering Science - «Development of methods for alternative production and use of carbonaceous reducing agent in Kazakhstan». Karaganda, 2010.