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                                          Ê.á.í. Gabaev D.D.

A.V. Zhirmunsky Institute of Marine Biology, Far eastern  Branch, Russian     

                         Academy of  Sciences, Vladivostok, Russia

The certain covering of conductors can aid in problems

      related to room-temperature superconductivity

 Keywords: coated metallic conductors, room-temperature superconductivity

ABSTRACT: High – temperature superconductors are required in many fields of modern technology. However theirs widespread are prevent of complexity creation of low consistent temperature for superconductors and work content theirs preparation and operation. I measured the electrical resistance of a number of metallic conductors, which I coated with materials of varying compositions and the are found that when nichrome wires were covered with clean bone glue, there was a conspicuous decrease in this resistance; with conductors containing iron covered with clean bone glue, the resistance decreased to zero.

                                            Introduction

        Many useful mechanisms and devices are not created because the problem of room - temperature superconductivity is not solved. Till now superconductors should be cooled by liquid nitrogen, that considerably complicates of their use. However my analysis of the literature has allowed to conclude, that for occurrence of superconductivity the low temperature is not obligatory. The following pieces of evidence support the above hypothesis. the discovery of high-temperature superconductivity in the mid-1980s1,2 overthrew the idea of temperature being a major factor in producing superconductivity. it became clear that a great deal depends on the composition of the doping used in such conductors1,2,3. studies of the internal structure of cuprates and pnictides led researchers to the idea that a superconductor is a hamburger, in which the electric current flows through the “meat,” while the “buns” act as a supplier of electrons4. The meat in those crystal sandwiches is represented by layers of copper oxide or iron pnictides, composed of alternating layers of atoms. examination under high magnification of the thin films that cover the crystal substratum revealed that the cuprate coating consists of spiral ladders with a screw displacement; this structure produced twisting in the lines of the magnetic field and facilitated high-temperature superconductivity5. In the Cuo2 layers, all the atoms were at almost the same level. However, in the FeAs layers, the arsenic atoms were situated above or below the iron atoms, and four arsenic atoms, surrounding each iron atom, were located at the tops of a tetrahedron6,7. The crystal lattices of recently synthesized superconductors also have a tetragonal structure8,9,10. Approaching the critical temperature for creation the tetragonal structure appears to be an important factor in the superconductivity of pnictides6,7,8. It appears likely that the pyramidal structure protects the conductor from the noise produced by electromagnetic and sound waves, which cause oscillations in the positive ions and thereby hinder the flow of electrons. It has long been known that placing conductors within a pyramid increases the temperature at which superconductivity appears11. a number of studies have investigated the changes in the long-range stripe-similar sequence at the critical temperature, which promotes the occurrence of high-temperature superconductivity12. quasiparticle interference, in which particle-like behavior disappears as a result of defects in a material, creates standing waves and promotes superconductivity13. Based on the above observations, I conclude that when a conductor is isolated from electromagnetic and sound waves, the positive ions in the conductor’s crystal lattice go into a dormant state and do not impede the flow of electrons. And I began to test various materials as a covering for conductors.

                                                    Results

      It was found that in a 0.2-mm-diameter nichrome wire, which was coiled into a spiral with a 7-mm diameter and covered with the experimental composition, the electrical resistance did not decrease at ordinary room temperature. The electrical resistance likewise showed no reduction when the wire in the spiral was stretched to twice its original length. this was probably due to the magnetic field generated by the electric current as it passed through the spiral wire. It has long been known that magnetic fields destroy superconductivity4. The experimental coatings decreased the resistance after the wire was wound into large coils (100.0 mm in diameter) or folded in the form of a zigzag. With the iron wire, the resistance decreased to zero (Fig.1).

      The initial resistance of the water heater with the stainless steel sheath was 6.3 ohms; after the sheath was coated with a 0.5-mm-thick layer of bone glue, resistance in the sheath decreased to zero at room temperature. The bone glue is an insulator. electrical resistance in a 1.5-mm-diameter iron wire after the bone glue as well decreased to zero at room temperature (fig. 2).

Thinning the layer of bone glue to a thickness of 0.05 mm caused the resistance in the sheath to increase to 4.5 ohms. However, after the heater was covered with Moment rubber glue and then allowed to dry, the resistance once again decreased to zero. Placing ordinary magnets on the heater did not affect its the electrical resistance. Five days after the conducting the resistance measurements, I repeated the tests, and the results I obtained were close to the initial ones.

     There was a statistically significant difference between the initial electrical resistance in the nichrome wires and the resistance after coating: t (40)= 3.409; df = 39; p = 0.0015. When the nichrome wire was covered with bone glue, the difference between the initial electrical resistance in the nichrome wires and the resistance after coating was as follows: t (11) = 2.32; df = 10; p = 0.043. When the nichrome wire was covered with Moment rubber glue, the difference between the initial electrical resistance in the nichrome wires and the resistance after coating was as follows: t (10) = 2.88; df = 9; p = 0.018. Non-metric multidimensional scaling analysis showed that the coating of bone glue and mixture of bone glue with Ca (H2PO4)2 + CaCO3 produced the greatest decrease in resistance in the nichrome wire (Fig. 3).

      Under a scanning electron microscope, it was evident that the various coatings showed defects in their structure; these defects were 0.5–40.0 µm in size (Fig. 4). the coating that provided the greatest decrease in resistance in the nichrome wire (bone glue) had defects that measured about 1.0 µm.       

                                             discussion

       High–temperature superconductors are used in many fields of modern technology. However, several obstacles prevent the widespread use of such superconductors. The first of these is the complex issue of creating constant low temperatures that allow the superconductors to function properly4. It has been reported that superconductors containing iron (pnictides) require lower temperatures than cuprates6.

       There is an ongoing search for new materials that can function as superconductors2,3; however, solving the problem of room-temperature superconductivity has reached an impasse. practically all existing inorganic substances have been subjected to trials as part of this search, but no superconductivity at room temperature has been found14. previous research efforts have examined the phenomenon of superconductivity particularly with regard to the doping used in the conductors1,2, and it has emerged that such a doping should certainly not be metallic6,9. However, no tests have been conducted on a coating similar to bone tissue.

        I covered metallic conductors with several kinds of coatings that had essentially a similar composition to that of the cranial bones. My results showed that when nichrome wires were coated, there was a significant reduction in the electrical resistance. the greatest reduction in resistance was observed when the wires were covered by clean bone glue. When this coating was used on iron conductors, the electrical resistance was reduced to zero.

                                          Conclusion

        In the present study, I have demonstrated that when coated with bone glue, metallic conductors exhibit considerably decreased electrical resistance at room temperature; when the conductor contained iron, the resistance fell to zero. covering conductors with a thin layer of bone glue plus Moment rubber glue imparted elasticity, resistance to impact, and stability to moisture and magnetic fields without loss of superconductivity. the results of this study demonstrate that it is possible to create a covering for conductors that decreases electrical resistance to zero.

                                             methods

 To determine the possible influence of a covering on the conductivity of metals, I covered metal conductors with bone glue, which has been used by carpenters over the past century for gluing wood. Bone is a calcified connective tissue, composed of cells within a solid basic substance. Approximately 30% of this basic substance consists of organic compounds, mostly in the form of collagen fibers, and the remaining 70% is inorganic. The major inorganic component of bone is hydroxyapatite—Ca10 (PO4)6 (OH)2, but bone also contains various amounts of sodium, magnesium, potassium, chlorine, fluorine, carbonates, and citrates15. To determine the optimum coatings for the conductors, I tested several compounds, including pure bone glue.

Instruments. For the conductors, I used mostly nichrome and iron wires and also a foreign-made immersion water heater with a stainless steel sheath (Weltor, Inc.). To measure the resistance of the conductors, I utilized a household multimeter, DT-831 (ASD-Electro, Inc.) with a range of 200 ohms and resolution of 0.1 ohm. The conductor coatings: pure bone glue; a dried mixture of superphosphate—Ca(H2PO4)2—and chalk (CaCO3); a mixture of bone glue and CaCO3 + Ca (H2PO4)2; a mixture of bone glue and superphosphate—Ca (H2PO4)2 were examined using a scanning electron microscope, EVO-40 (Carl Zeiss, Inc. germany)

Making bone glue and mixtures. I made the pure bone glue coating using a thermostatic water bath (in capacity with water capacity with glue and water is placed) by fusing bone glue granules (bone glue, Usolsk Glue Factory, Russia) in water at a weight ratio of 1:1 and at a temperature of 65–70°Ñ. The bone glue mixtures were produced using the thermostatic water bath by mixing the bone glue with salts or Moment rubber glue (produced of Henkel AG & Co. KGaA, germany).

Coating variants. First, the resistance of 0.2-mm-diameter nichrome wire was measured. This wire was then dipped into the following: (1) Moment rubber glue; (2) bone glue, which had been melted in the thermostatic water bath; (3) humidified superphosphate—Ca (H2PO4)2—which was mixed with the melted bone glue in the proportion of 50:50; (4) a mixture in which three-quarters of the volume was CaCO3 + Ca (H2PO4)2 and one-quarter was melted bone glue; (5) a mixture in which three-quarters of the volume was melted bone glue and one-quarter was Moment rubber glue. The pieces of wire were immersed in the glue for no longer than one minute. Resistance was measured in a 1.5-mm-diameter iron wire as well as in the water heater, in which the diameter of the stainless steel sheath was 4.0 mm. Then, the pieces of wire were immersed in the melted bone glue. After being removed from the glue, the conductors were air-dried for six hours, following which their resistance was measured. After removal from the water bath, the thickness of bone glue at water heater was 0.5 mm. I then decreased the thickness of the bone glue layer to 0.05 mm by immersion in the hot water. After drying the conductor again, I measured the resistance of the sheath, then dipped the conductor in the Moment rubber glue, dried it, and again measured the resistance. I then attached several household magnets to the sheath and measured the resistance.

Statistics. Data were analyzed using the Statistica statistical package (6.0 Version). The results were expressed as means and with a 95% confidence interval. The Kolmogorov-Smirnov test was employed to analyze the normal distribution of the variables (p < 0.05). The data followed a normal distribution and were therefore analyzed using parametric tests. Student’s t test for dependent samples was utilized to assess the differences in the resistance of electric current in the nichrome wires before and after the coverings were applied. For graphical representation of the data, non-metric multidimensional scaling ordination was carried out using the Bray-Curtis distance. before calculation, the data were transformed according to the method adopted by16. For each variant, I coated 5–11 nichrome wires. In all, 40 wires were employed.

 

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Figure 1. Variations in the electrical resistance (ohms, 20°C) of conductors with various coatings. The control instrument reading in the experiments was with the absence of a conductor. (A) Resistance in the 4.0-mm-diameter sheath of the water heater before (black) and after (white) coating with bone glue; (B) resistance in a 1.5-mm-diameter iron wire before (black) and after (white) coating with bone glue; (c) resistance in a 0.2-mm- diameter nichrome wire before (black) and after (white) coating with bone glue; (d) resistance in a 0.2-mm- diameter nichrome wire before (black) and after (white) coating with Moment rubber glue; (e) resistance in a 0.2-mm-diameter nichrome wire before (black) and after (white) coating with a mixture of bone glue and Moment rubber glue; (f) resistance in a 0.2-mm-diameter nichrome wire before (black) and after (white) coating with a mixture of salts—Ca (H2PO4)2 + CaCO3—and bone glue; (g) resistance in a 0.2-mm-diameter nichrome wire before (black) and after (white) coating with a mixture of superphosphate—Ca(H2PO4)2—and bone glue.

image description

 

 

 

 

Figure 2. Measuring electrical resistance (ohms, 20°C) in a conductor containing iron. (a) The control instrument reading in the experiments was with the absence of a conductor; (b) electrical resistance in the sheath of the water heater before the covering was applied; (c) electrical resistance in the sheath of the water heater after the bone glue was applied; (d) electrical resistance of the covering; (e) electrical resistance in a 1.5-mm-diameter iron wire before the covering was applied; (f) electrical resistance in a 1.5-mm-diameter iron wire after the bone glue was applied.

 

Figure 3. Non-metric multidimensional scaling ordination analyses of electrical resistance in the nichrome wires before and after the different coatings were applied. Bonbef = befor covering of bone glue, bonaft = after covering of bone glue, mombef = befor covering of Moment rubber glue, momaft = after covering of Moment rubber glue, sulbef = befor covering of a mixture of salts and bone glue, sulaft = after covering of a mixture of salts and bone glue.

image description

 

Figure 4. View of the coatings at high magnification. (a) The pure bone glue had cavities owing to microbubbles of air; (b) dried salts—Ca (H2PO4)2 + CaCO3—obtained by mixing with water under carbon dioxide aeration show no structural disturbances; (c) the mixture of bone glue and salts—Ca (H2PO4)2 + CaCO3—displays disturbances in its structure; (d) the mixture of bone glue and superphosphate—Ca (H2PO4)2—had disturbances in its structure.